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GaAs - Gallium Arsenide

American Photonics multispectral zinc sulfide is a form of CVD zinc sulfide that is subjected to a post-deposition hot isostatic process. This Removes zinc hydrides from the crystal lattice, normalizes crystal structure and purifies the material, thus creating a virtually clear substrate with high transmission and minimal scatter from 0.4 to 12 microns. When several wavebandsand a single crystal are required, multispectral zinc sulfide has become the material of choice.

APC can provide raw or generated blanks to most customer specificatons. Circular, square or rectangular geometries are available. See APC's capabilities with optical fabrication and film coatings for more details.

Physical Properties  
   
Crystal structure Cubic
Grain size (diameter) 20-35 µm
Density (g cm-3 @298k) 4.09
Resitivity (Ωcm) >1013
Chemical Purity (%) 99.996
Dielectic constant data is available from Morton in technical bulletin #103
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Mechanical Properties
Hardness:
Knoop, 50gm load (kg mm-2)
160
 
Vickers, 1kg load (kg mm-2)
150
Flexural Strength (modulus of rupture)
 
4pt. loading (psi)
10X10
 
4pt. loading (MPa)
60
 
Disc. Bursting (MPa)
50
Fracture toughness (critical stress intensity factor, Kic values)
  (MPa √m, Vicers, 1 Kg)
1.0
Young's modulus (elastic modulus)
  (psi)
10.8X10
  (GPa)
74.5
Poisson's ratio
0.28
Rain erosion resistance will depend on the environment
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Thermal Properties
Coefficient of Thermal Expansions  
  (K1 @ 273K) 6.3 X 10-6
  (K1 @ 373K) 7.0 X 10-6
  (K1 @ 473K) 7.5 X 10-6
  (K1 @ 208-573 K)) 6.5 X 10-6
Thermal Conductivity  
  JK-1m-1s-1 @298 K) 27.2
Heat Capacity  
  Jg-1 K @ 273 K 0.515
  Jg-1 K @ 323 K 0.527
  Jg-1 K @373 K 0.527
Thermal Diffusivity(m2s-1   1.3 X 10-5
Maximum operating temperature will depend on the environment
     
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Optical Properties
10% transmission limits (t=6mm) 0.37 - 14µm
Index of refraction in homogeneity (∆ n/n)  
  (ppm @ 0.6328 µm) <20
Thermo-optic coefficient, dn/dt (298-358K)  
(avg. values)    
  K -1 @ 0.6328 µm 5.43 X 10-5
  K -1 @ 0.1.15 µm 4.21 X 10-5
  K -1 @ 0.3.39 µm 3.87X 10-5
Bulk absorbstion coefficient  
  (cm-1 @ 1.3 µm) 6.0 X 10-1
  (cm-1 @ 2.7 µm) 1.0 X 10-1
  (cm-1 @ 3.8 µm) 6.0 X 10-1
  (cm-1 @ 9.27 µm) 6.0 X 10-1
  (cm-1 @ 10.6 µm) 2.0 X 10-1